| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5280296 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
A series of enantiomerically enriched functionalised pyrans bearing a dicobalt hexacarbonyl-alkyne moiety have been subjected to a Lewis acid mediated rearrangement to carbocyclic ketones. This process was found to provide cyclohexanones with good enantioselectivity, however, cyclobutanones were generated with complete loss of enantiocontrol.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Simon J. Meek, Emmanuel H. Demont, Joseph P.A. Harrity,