Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5280797 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
It was found by X-ray diffraction and NMR studies that the structure of the adduct of bis-ortho-methyl-bis-para-methyl substituted Tröger base and dimethyl acetylenedicarboxylate is a [3.3.1]bicyclic compound corresponding to the methyl 13-[1-(methoxycarbonyl)vinyl]-13-carboxylate. Chemical and NMR evidence supported similar structures for all other reported adducts of Tröger bases and activated acetylenes.
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Authors
D.A. Lenev, I.I. Chervin, K.A. Lyssenko, R.G. Kostyanovsky,