| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5280808 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
An alternative strategy has been developed for producing 3-azido-2,3,6-trideoxy-l-hexoses, protected forms of daunosamine, ristosamine, acosamine, and epi-daunosamine. This method involved BF3·OEt2-induced peroxidation of rhamnal to construct key intermediate α,β-unsaturated lactone as the common precursor. After further derivatization, four 3-azido hexoses were successfully synthesized.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Guisheng Zhang, Lei Shi, Qingfeng Liu, Xiaobing Liu, Lu Li, Jingmei Wang,