Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5280856 | Tetrahedron Letters | 2010 | 4 Pages |
Abstract
The phenyl group incorporated into a carbon tether provides for the synthesis of 1,5-cyclodecadiynes with 95–100% d,l-diastereoselectivity due to intrinsic conformational constraints and preorganization of the Co2(CO)6-complexed propargyl intermediates.
Graphical abstractThe phenyl group incorporated into a carbon tether provides for the synthesis of 1,5-cyclodecadiynes with 95–100% d,l-diastereoselectivity due to intrinsic conformational constraints and preorganization of the Co2(CO)6-complexed propargyl intermediates.Figure optionsDownload full-size imageDownload as PowerPoint slide
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