Article ID Journal Published Year Pages File Type
5280856 Tetrahedron Letters 2010 4 Pages PDF
Abstract

The phenyl group incorporated into a carbon tether provides for the synthesis of 1,5-cyclodecadiynes with 95–100% d,l-diastereoselectivity due to intrinsic conformational constraints and preorganization of the Co2(CO)6-complexed propargyl intermediates.

Graphical abstractThe phenyl group incorporated into a carbon tether provides for the synthesis of 1,5-cyclodecadiynes with 95–100% d,l-diastereoselectivity due to intrinsic conformational constraints and preorganization of the Co2(CO)6-complexed propargyl intermediates.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry