Article ID Journal Published Year Pages File Type
5280987 Tetrahedron Letters 2008 4 Pages PDF
Abstract

The Wacker-type oxidation is an important procedure catalyzed by palladium complexes. A mild and general method for the preparation of β-substituted-δ-oxosulfoxides from the corresponding β-substituted-γ,δ-unsaturated sulfoxides is described. The products are versatile synthetic intermediates for the preparation of syn- and anti-1,3-diol and 1,3-aminoalcohol derivatives.

Graphical abstractA mild and general method for the preparation of β-substituted-δ-ketosulfoxides by a Wacker type reaction is described.Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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