Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5280987 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
The Wacker-type oxidation is an important procedure catalyzed by palladium complexes. A mild and general method for the preparation of β-substituted-δ-oxosulfoxides from the corresponding β-substituted-γ,δ-unsaturated sulfoxides is described. The products are versatile synthetic intermediates for the preparation of syn- and anti-1,3-diol and 1,3-aminoalcohol derivatives.
Graphical abstractA mild and general method for the preparation of β-substituted-δ-ketosulfoxides by a Wacker type reaction is described.Download full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sadagopan Raghavan, V. Krishnaiah, Kailash Rathore,