| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5281117 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
5-Alkyl-2-methyl-2-carbomethoxy-1,3-dioxanes were found to have a cis preferential configuration in the equilibrium state, and the ester hydrolysis rate of the trans-isomers was faster than that of the cis-isomers. Conformational analysis and charge calculation of the carbomethoxy group in both dioxanes elucidated this selectivity.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Tetsuji Harabe, Takatoshi Matsumoto, Takayuki Shioiri,