| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5281155 | Tetrahedron Letters | 2005 | 6 Pages |
Abstract
A convenient and efficient C-H insertion reaction of environment friendly H2O2 into representative hydrocarbon derivatives by homogeneous methyltrioxorhenium (MTO), heterogeneous poly(4-vinylpyridine)/methyltrioxorhenium (PVP/MTO) and microencapsulated polystyrene/methyltrioxorhenium (PS/MTO) systems in ionic liquids, is described. In some cases a higher activity was observed if compared with the same reaction in molecular solvents. The heterogeneous catalysts are stable systems under the reaction conditions and can be recycled for more transformations.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gianluca Bianchini, Marcello Crucianelli, Francesco De Angelis, Veronica Neri, Raffaele Saladino,