Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5281274 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The first synthesis of allenylselenonium salts and their reactivities are described. The corresponding allenyl methyl selenides were alkylated with methyl trifluoromethanesulfonate to afford the desired compounds. Their reactions with active methylene carbanions produced furan, dihydrofuran or methylene cyclopropane derivatives via the Michael addition of nucleophiles to the selenonium salts.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shin-ichi Watanabe, Yukio Miura, Tatsunori Iwamura, Hideko Nagasawa, Tadashi Kataoka,