| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5281470 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
Organozinc reagents (organozinc halides, diorganozincs and mixed copper-zinc reagents) react with β-(allyloxy)-enoates via a radical-polar crossover process to afford substituted furans in one single synthetic step following a domino reaction involving Michael addition and carbocyclisation. Reversal of diastereoselectivity can be obtained varying the organometallic and/or the reaction conditions.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Steven Giboulot, Alejandro Pérez-Luna, Candice Botuha, Franck Ferreira, Fabrice Chemla,
