| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5281475 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
An exceptional intramolecular palladium-catalyzed alkenylation of silyl enol ether in the absence of a fluoride additive was developed, and this reaction led to the construction of bicyclo[3.3.1]nonane ring system in reasonable yield. In this type of reactions, trialkylamines were employed as additives instead of previously indispensable fluoride additives.
Graphical abstractAn infrequent intramolecular palladium-catalyzed alkenylation of silyl enol ether in the absence of a fluoride additive was developed leading to a construction of bicyclo[3.3.1]nonane ring system in reasonable yield.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hiroki Shigehisa, Takaaki Jikihara, Osamu Takizawa, Hiromasa Nagase, Toshio Honda,