| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5281769 | Tetrahedron Letters | 2006 | 5 Pages |
Abstract
Nucleophilic addition of the pentafluorophenyl group from (C6F5)3SiF to non-activated imines affording α-C6F5-substituted secondary amines in high yield has been described. The reaction proceeds via simultaneous activation of imines and the silane reagent by means of a proton and chloride ion, respectively.
Graphical abstractNucleophilic addition of the C6F5-group to non-activated imines is described.Download full-size image
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vitalij V. Levin, Alexander D. Dilman, Pavel A. Belyakov, Marina I. Struchkova, Vladimir A. Tartakovsky,