Article ID Journal Published Year Pages File Type
5281777 Tetrahedron Letters 2006 5 Pages PDF
Abstract

Microwave promoted synthesis of novel imidazolium-based ionic liquid crystalline dimers containing calamitic-calamitic, calamitic-discotic and discotic-discotic moieties is reported. Classical reactions failed to produce these dimers. The thermotropic liquid crystalline properties of these salts were investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray diffractometry. These salts, except the one having calamitic-discotic units, with bromide as counter ion were found to be mesomorphic over a wide temperature range.

Graphical abstractMicrowave promoted synthesis of novel imidazolium-based ionic liquid crystalline dimers containing calamitic-calamitic, calamitic-discotic and discotic-discotic moieties has been described.Download full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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