Article ID Journal Published Year Pages File Type
5281922 Tetrahedron Letters 2008 5 Pages PDF
Abstract

A highly efficient protocol for the Pd-catalyzed regioselective Heck arylation of the electron-rich olefin N-acyl-N-vinylamine with aryl halides has been developed. In the presence of hydrogen-bond donor [H2NiPr2][BF4] as an additive, this proceeds smoothly in isopropanol to afford exclusively the branched products in high yields.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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