Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282022 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
An Ir-catalyzed asymmetric allylic amination using chiral diaminophosphine oxide is described. Asymmetric allylic amination of terminal allylic carbonates proceeded in the presence of 2 mol % of Ir catalyst, 2 mol % of chiral diaminophosphine oxide, 5 mol % of NaPF6, and BSA, affording the chiral branched allylic amines in up to 95% ee.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Tetsuhiro Nemoto, Tatsurou Sakamoto, Takayoshi Matsumoto, Yasumasa Hamada,