| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5282065 | Tetrahedron Letters | 2009 | 5 Pages |
Abstract
The first stereoselective total synthesis of synargentolide A isolated from Syncolostemon argenteus has been achieved from commercially available (R)-benzyl glycidyl ether using Sharpless asymmetric epoxidation and cross-metathesis reactions as the key steps. Comparing the spectral data of the synthesized and naturally occurring synargentolide A, the C4â² and C6â²- stereogenic centers of the natural synargentolide A were assigned a corrected anti relationship.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gowravaram Sabitha, Peddabuddi Gopal, C. Nagendra Reddy, J.S. Yadav,