Article ID Journal Published Year Pages File Type
5282153 Tetrahedron Letters 2007 4 Pages PDF
Abstract

The synthesis of 4a-carba-β-d-galactofuranose is described starting from diacetone glucose. The key ring-closure step was carried out by metathesis to form a cyclopentene. Catalytic hydrogenation of the CC double bond gave the galacto configured saturated carbahexofuranose with excellent diastereoselectivity.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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