Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282165 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Ketones and aldehydes were effectively reduced to the corresponding alcohols (or their silyl ethers) by the reaction with CaH2 and R3SiCl in the presence of a catalytic amount of ZnCl2. In the absence of the carbonyl substrate, the reagent reduced R3SiCl to the corresponding hydrosilane under mild reaction conditions.
Graphical abstractKetones and aldehydes were effectively reduced to the corresponding alcohols (or their silyl ethers) by the reaction with CaH2 and R3SiCl in the presence of a catalytic amount of ZnCl2. In the absence of the carbonyl substrate, the reagent reduced R3SiCl to the corresponding hydrosilane under mild reaction conditions.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Akiko Tsuhako, Jing-Qian He, Mariko Mihara, Naoko Saino, Sentaro Okamoto,