| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5282185 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
In situ-generated N-heterocyclic carbene (NHC) palladium catalysts and isolated NHC-palladium complexes have been tested for the telomerization reaction of 1,3-butadiene with primary and secondary amines. Superior catalyst activity (TON up to 400.000) and selectivity are obtained. Applying optimized conditions a variety of octa-2,7-dienylamines were prepared in high yield and excellent selectivity.
Graphical abstractPd/NHC catalysts show unprecedented high catalyst efficiency in telomerization reactions of 1,3-butadiene with amines.Figure optionsDownload full-size imageDownload as PowerPoint slide
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