Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282256 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Protodesilylaton of substituted silyl dithianes occurs with clean retention of configuration. In the case of the 2-phenyl derivative, epimerization of C-2 occurs. Selective functionalization of 2,2-bis trimethylsilyl derivatives can be efficiently obtained.
Graphical abstractProtodesilylation of different substituted silyl dithianes occurs with a clean retention of configuration.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vanda Cerè, Antonella Capperucci, Alessandro Degl'Innocenti, Salvatore Pollicino,