| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5282273 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
A catalytic enantioselective Strecker-type reaction to N-(2-pyridylsulfonyl)imines in the presence of chiral bis(oxazoline)s afforded the products with a high enantioselectivity. A dynamically induced new chiral center on the sulfur by discriminative coordination of a chiral Lewis acid to one of the sulfonyl oxygens efficiently controlled the enantioselectivity.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shuichi Nakamura, Hiroki Nakashima, Hideki Sugimoto, Norio Shibata, Takeshi Toru,