Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282425 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
In the presence of Pd catalyst, 3-imidazoline nitroxyl radicals promote oxidative coupling (dimerization) of terminal alkynes even in the absence of Cu(II) additives. On the other hand, the Pd-free CuI-PPh3-K2CO3-DMF catalytic system leads to the efficient cross-coupling of 1-hydroxy-4-[2-(p-iodophenyl)vinyl]-2,2,5,5-tetramethyl-3-imidazoline-3-oxide with terminal aryl- and hetarylacetylenes with the formation of 4-[2-(aryl/hetarylethynyl)phenyl)vinyl]-2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyls in 70-75% yields.
Related Topics
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Authors
Sergei F. Vasilevsky, Olga L. Krivenko, Igor V. Alabugin,