Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282609 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
Asymmetric desymmetrization of meso-vic-diols was performed by tosylation in the presence of copper(II) triflate and (R,R)-Ph-BOX as a catalyst. The method was successfully applied to asymmetric desymmetrization of cyclic and acyclic meso-vic-diols in high enantioselectivity with up to >99% ee.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yosuke Demizu, Kazuya Matsumoto, Osamu Onomura, Yoshihiro Matsumura,