Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5282744 | Tetrahedron Letters | 2009 | 4 Pages |
Abstract
Mixed cyclisations have been performed to give phthalocyanine-naphthalocyanine hybrids bearing solubilising substituents. Reactivity differences between the two phthalonitrile precursors result in inefficient mixed-macrocyclisation under standard, non-templating conditions leading to predominant formation of symmetrical phthalocyanine. Templated mixed-macrocyclisation leads to the hybrids. However, the reaction proceeds with unexpected selectivity with only one of the possible 2:2 products observed.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andrew N. Cammidge, Victoria H.M. Goddard, Geoffrey Will, Dennis P. Arnold, Michael J Cook,