Article ID Journal Published Year Pages File Type
5282921 Tetrahedron Letters 2009 4 Pages PDF
Abstract
New terphenyl-based derivative 4 with pyrene as a fluorophore has been synthesized and examined for its cation recognition abilities toward various cations by NMR and fluorescence spectroscopy. The results show that it has very high binding affinity (log β = 5.12) and selectivity for mercury. A fluorescence enhancement of 375% was observed for the 4-Hg2+ system in THF. The lower limit of detection is 2.1 × 10−6 M.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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