| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5282955 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The palladium complex prepared in situ from [Pd(η3-C3H5)(cod)]BF4 and bidentate phosphine DPPF was a good catalyst for the nucleophilic substitution of benzyl acetate. Significant acceleration of the palladium-catalyzed substitution was observed when an alcohol was employed as a reaction solvent. The palladium catalyst was effective for the benzylation of various stabilized carbanions, amines, and benzenesulfinate with benzylic acetates.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Masashi Yokogi, Ryoichi Kuwano,