Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5283365 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
The water-soluble copper complex generated in situ from CuCl2 and 2,2â²-biquinoline-4,4â²-dicarboxylic acid dipotassium salt (BQC), has been revealed as a highly efficient and selective catalyst for the oxidation of secondary 1-heteroaryl alcohols to the corresponding heteroaromatic ketones with aqueous tert-butyl hydroperoxide, under mild conditions. The catalytic system is compatible with different heterocycles such as pyridines, pyrroles, indoles, thiophens, furans, thiazoles, and imidazoles.
Related Topics
Physical Sciences and Engineering
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Authors
Josée Boudreau, Mike Doucette, Abdelaziz Nait Ajjou,