Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5283806 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
The addition of several trialkyl or triarylindium reagents to the acetates of Baylis-Hillman adducts proceeds readily under the catalysis of copper and palladium derivatives. The reactions of trialkylindiums are catalyzed efficiently by CuI whereas additions of triarylindiums produce better results with Pd(PPh3)4. The reactions with 3-acetoxy-2-methylenealkanoates provide (E)-alkenes, whereas similar reactions with 3-acetoxy-2-methylenealkanenitriles lead to (Z)-alkenes. All the reactions are highly regio- and stereoselective and high yielding.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Brindaban C. Ranu, Kalicharan Chattopadhyay, Ranjan Jana,