Article ID Journal Published Year Pages File Type
5283808 Tetrahedron Letters 2007 4 Pages PDF
Abstract
Using CrCl2 in THF at room temperature, trichloromethyl carbinols and trichloromethylalkanes are readily transformed to the highly reactive α-chlorocarbenes, carbynes, and α-chloro-α-chromium(III) vinylidene carbenoids. A mechanistic study is carried out to determine the nature of the intermediates.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, , , , ,