Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5283808 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Using CrCl2 in THF at room temperature, trichloromethyl carbinols and trichloromethylalkanes are readily transformed to the highly reactive α-chlorocarbenes, carbynes, and α-chloro-α-chromium(III) vinylidene carbenoids. A mechanistic study is carried out to determine the nature of the intermediates.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Romain Bejot, Steve Tisserand, De Run Li, J.R. Falck, Charles Mioskowski,