Article ID Journal Published Year Pages File Type
5284340 Tetrahedron Letters 2008 4 Pages PDF
Abstract
A synthesis of (−)-crobarbatic acid is reported along with the first use of a vinyl-substituted ketene dithioacetal as a coupling partner for an anodic cyclization reaction. The use of the vinyl-substituted ketene dithioacetal enables the construction of a cyclic product having a tetrasubstituted carbon with a relative stereochemistry opposite to that originally obtained from the cyclization.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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