Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5284340 | Tetrahedron Letters | 2008 | 4 Pages |
Abstract
A synthesis of (â)-crobarbatic acid is reported along with the first use of a vinyl-substituted ketene dithioacetal as a coupling partner for an anodic cyclization reaction. The use of the vinyl-substituted ketene dithioacetal enables the construction of a cyclic product having a tetrasubstituted carbon with a relative stereochemistry opposite to that originally obtained from the cyclization.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hai-Chao Xu, John D. Brandt, Kevin D. Moeller,