Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5284457 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
Rh(CO)2(acac)/TangPhos was found to be a highly enantioselective catalyst for asymmetric hydroformylation of norbornylene under mild conditions. Application of the protocol to the desymmetrization of other [2.2.1]-bicyclic olefins gave moderate to excellent enantioselectivity (55-92% ee).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jinkun Huang, Emilio Bunel, Alan Allgeier, Jason Tedrow, Thomas Storz, J. Preston, Tiffany Correll, Deana Manley, Troy Soukup, Randy Jensen, Rashid Syed, George Moniz, Robert Larsen, Michael Martinelli, Paul J. Reider,