Article ID Journal Published Year Pages File Type
5284497 Tetrahedron Letters 2006 4 Pages PDF
Abstract
Vinyl tridecafluorohexyl sulfoxide 1 and sulfone 2 are shown to be highly reactive towards Michael addition with a broad range of secondary and primary amines. Full selectivity for monofunctionalization of primary amines can be achieved by a proper choice of reagent 1 or 2 depending on amine basicity.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Selective Michael additions of primary and secondary amines to perfluoroalkylated sulfoxides and sulfones as a tool for fluorous tagging
Authors
, , , ,