| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5285181 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Syntheses of highly substituted thiophenol derivatives that incorporate steric bulk into the ligand framework via ortho- and para-tert-butyl substituents are reported. S-Benzyl and trityl protection were investigated and the effects of substituents on the Newman-Kwart rearrangement of the thiocarbamate discussed. Single crystal X-ray structures are reported for three compounds and they demonstrate the role of hydrogen bonding in stabilising the thiophenol to oxidation.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gary Nicholson, Jon D. Silversides, Stephen J. Archibald,