Article ID Journal Published Year Pages File Type
5285182 Tetrahedron Letters 2006 4 Pages PDF
Abstract
A stereocontrolled synthesis of the IJK ring segment of yessotoxin is described. Cyclization of 11 mediated by SmI2 gave the IJ ring system 12 as the sole product. Construction of the K ring moiety was performed by the acid catalyzed cyclization of epoxy alcohol 20 to afford the IJK ring segment in a highly stereocontrolled manner.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
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