Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5285191 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
Unprecedented magnesium dihalide-catalysed Claisen rearrangement of 2-alkoxycarbonyl allyl vinyl ethers derived from α-chloroglycidic esters is reported in the glucidic series. A first application of this reaction concerns the stereoselective construction of a disaccharide analogue including a galactosyl and an ulosonic isopropyl ester moieties.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Claude Grison, Tomasz K. Olszewski, Céline Crauste, Alain Fruchier, Claude Didierjean, Philippe Coutrot,