Article ID Journal Published Year Pages File Type
5285434 Tetrahedron Letters 2005 6 Pages PDF
Abstract
The first enantiospecific total synthesis of gardnerine and gardnutine has been achieved from 6-methoxy-d-tryptophan via the asymmetric Pictet-Spengler reaction, a stereocontrolled intramolecular enolate driven palladium-mediated cross-coupling reaction and a chemospecific, regiospecific hydroboration/oxidation sequence as key steps.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
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