| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5285831 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
The conjugate addition of protected pyranose alkoxides to 1-nitro- and 1-nitrosoalkenes gave 2-nitroalkyl and 2-oximinoalkyl glycosides. In several cases, the reaction proceeded with preferential formation of the α-glycoside (α:β ⩽ 4:1). The methodology was employed in model (L)-rhodinosylation reactions relevant to the total synthesis of lactonamycin.
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Authors
Gary Trewartha, Jeremy N. Burrows, Anthony G.M. Barrett,