Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5285916 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
The epoxidation of phosphinoyl alkenes with H2O2 was significantly affected by the structure of the phosphorus compounds. While alkenylphosphonates and phosphinates having α-phenyl group reacted with H2O2/K2CO3, alkenylphosphonic, and phosphinic acids having an aliphatic group at α- or β-positions reacted with H2O2/Na2WO4/Et3N to produce high yields of the corresponding epoxides.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yutaka Ono, Li-Biao Han,