Article ID Journal Published Year Pages File Type
5285916 Tetrahedron Letters 2006 4 Pages PDF
Abstract
The epoxidation of phosphinoyl alkenes with H2O2 was significantly affected by the structure of the phosphorus compounds. While alkenylphosphonates and phosphinates having α-phenyl group reacted with H2O2/K2CO3, alkenylphosphonic, and phosphinic acids having an aliphatic group at α- or β-positions reacted with H2O2/Na2WO4/Et3N to produce high yields of the corresponding epoxides.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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