Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5286402 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
The tricyclic ketone 1, which displays the ring system of cyathin diterpenes was assembled from 2-methylcyclopentanone through a sequence involving enantioselective Michael addition, intramolecular Heck reaction and trimethylaluminum-promoted one-carbone ring expansion of the C-ring with trimethylsilyldiazomethane.
Related Topics
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Authors
Emmanuelle Drège, Georges Morgant, Didier Desmaële,