| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5286471 | Tetrahedron Letters | 2007 | 5 Pages |
Abstract
Palladium-1,2-bis(diphenylphosphino)ethane complex catalyzes regioselective Markovnikov addition of diphenylphosphine oxide to terminal alkynes in propionitrile, while the use of triarylphopshines, di(o-tolyl)phenylphosphine in particular, as the ligand leads to dehydrogenative double addition forming 1,2-diphenylphosphinyl-1-alkenes as major products.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Naotomo Dobashi, Kouichiro Fuse, Takako Hoshino, Jun Kanada, Taigo Kashiwabara, Chihiro Kobata, Satish Kumar Nune, Masato Tanaka,