Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5286717 | Tetrahedron Letters | 2007 | 4 Pages |
Abstract
Methyl(trifluoromethyl)dioxirane (TFDO, 1b) was employed to obtain triol 7 upon direct stereoselective hydroxylation of cis,cis-1,3,5-tri-methylcyclohexane. Starting with 7, the cage-shaped 'tripod' borate ester 8 was easily obtained; 7 also provided easy access to 10, a new kind of arylboronic Brönsted-assisted Lewis acids (BLA).
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lucia D'Accolti, Michele Fiorentino, Caterina Fusco, Francesco Capitelli, Ruggero Curci,