Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5286761 | Tetrahedron Letters | 2005 | 4 Pages |
Abstract
A novel type of coupling reaction has been developed by the palladium-catalyzed reaction of propargylic oxiranes with arylboronic acids, in which anti-substituted 4-aryl-2,3-allenols were produced in a highly diastereoselective manner. A chiral-substituted allene has been synthesized from the reaction of a chiral propargylic oxirane without loss of the chirality.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Masahiro Yoshida, Hirofumi Ueda, Masataka Ihara,