Article ID Journal Published Year Pages File Type
5286957 Tetrahedron Letters 2005 5 Pages PDF
Abstract
Co(acac)2·2H2O efficiently catalyzes SnCl2-mediated Barbier coupling in water between carbonyls, including aromatic, aliphatic and α,β-unsaturated aldehydes, ketones, sugars and allyl bromide to afford the corresponding homoallylic alcohols in high yields. The catalyst was reused for several cycles with consistent activity.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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