Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5286957 | Tetrahedron Letters | 2005 | 5 Pages |
Abstract
Co(acac)2·2H2O efficiently catalyzes SnCl2-mediated Barbier coupling in water between carbonyls, including aromatic, aliphatic and α,β-unsaturated aldehydes, ketones, sugars and allyl bromide to afford the corresponding homoallylic alcohols in high yields. The catalyst was reused for several cycles with consistent activity.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Mihir K. Chaudhuri, Sanjay K. Dehury, Sahid Hussain,