Article ID Journal Published Year Pages File Type
5287016 Tetrahedron Letters 2007 4 Pages PDF
Abstract
A stereoselective method has been developed for the synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts using polymethylhydrosiloxane (PMHS) and iodine in chloroform at room temperature. In addition, the reagent system has been utilized for the iodination of benzylic alcohols selectively.
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Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
An expedient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts along with selective iodination of benzylic alcohols using the polymethylhydrosiloxane-iodine system
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