Article ID Journal Published Year Pages File Type
5287353 Tetrahedron Letters 2007 4 Pages PDF
Abstract
Push-pull 2-alkylidene-4-oxothiazolidine vinyl bromides undergo efficient C(5) functionalization through DMSO-assisted carbon-bromine cleavage, followed by a bromine transfer-substitution (or elimination) sequence. A mechanism for this novel transformation is proposed.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Carbon-bromine cleavage by dimethyl sulfoxide: the key step of C(5) functionalization of push-pull 2-alkylidene-4-oxothiazolidine vinyl bromides
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