| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5288093 | Tetrahedron Letters | 2006 | 5 Pages |
Abstract
A new type of bis(free base porphyrin) 1, in which two porphyrin units are attached to the 5,5â²-positions of the 2,2â²-biphenyldiol group, has been synthesized. It exhibits exciton-coupled bisignate circular dichroism (CD) spectra upon interaction with chiral amino alcohols. The chiral information from the stereogenic center of amino alcohols is introduced as a twist of the porphyrin units in 1 via hydrogen bonding interactions, detectable by the signal in the CD spectrum. Based on these findings, it is proposed that 1 should serve as a reporter unit of chiral sensor systems.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yusuke Ishii, Yoichi Onda, Yuji Kubo,