Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5288105 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
A simple and easy method for chemoselective synthesis of hexopyranosyl acetates and 2,3-disubstituted tetrahydropyrans from hex-2-enopyranosyl acetates was demonstrated. The former was achieved by hydrogenation catalyzed by Rh/Al2O3 in EtOAc/toluene solvent at 0 °C, while the latter was carried out using Pd/C in EtOH/AcOH at 25 °C.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kaname Sasaki, Takayuki Wakamatsu, Shuichi Matsumura, Kazunobu Toshima,