| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5288373 | Tetrahedron Letters | 2017 | 5 Pages |
Abstract
The study of the Ï-facial diastereoselectivity in the [4+3] cycloaddition reaction of 13 chiral 2-substituted furans with oxyallyl cations is presented. A cis-endo diastereospecificity is observed and the Ï-facial diastereoselectivity increases by decreasing the distance between the chiral auxiliary and the reactive C2-carbon of the furan ring.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Induction of asymmetry on the [4+3] cycloaddition reaction of C2-functionalized furans](/preview/png/5288373.png "First Page Preview: Induction of asymmetry on the [4+3] cycloaddition reaction of C2-functionalized furans")
Authors
Angel M Montaña, Pedro M Grima,