Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5288902 | Tetrahedron Letters | 2006 | 5 Pages |
Abstract
Intermolecular hydroamination or hydroarylation reactions of norbornene and cyclohexadiene performed with catalytic amounts of Brönsted or Lewis acid in ionic liquids were found to provide higher selectivity and yields than those performed in classical organic solvents. The ionic liquid increases the acidity of the media and stabilizes ionic intermediates through the formation of supramolecular aggregates.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Alexandre A.M. Lapis, Brenno A. DaSilveira Neto, Jackson D. Scholten, Fabiane M. Nachtigall, Marcos N. Eberlin, Jairton Dupont,