| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5289067 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
The C13-C29 fragment of caribenolide I was prepared with a total control of the configuration of 5 stereogenic centres (out of 6). The key steps rely on the use of a chiral oxazolidin-2-thione for a highly diastereoselective C-glycosylation, and the vinylogous Mukayiama aldol reaction.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gaël Jalce, Xavier Franck, Blandine Seon-Meniel, Reynald Hocquemiller, Bruno Figadère,