Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5289623 | Tetrahedron Letters | 2006 | 4 Pages |
Abstract
A recyclable and reusable (S) diphenylpyrrolinol silyl ether I organocatalyst bearing a n-C8F17 fluorous tag has been demonstrated for promoting the asymmetric Michael addition reactions of a wide range of aldehydes with both aryl and alkyl-substituted nitroolefins and excellent levels of enantio- and diastereoselectivities are achieved. The catalyst I can be conveniently recovered by fluorous solid-phase extraction and subsequently reused (up to eight cycles) without significant loss of its catalytic activity and stereoselectivity for the process.
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Authors
Liansuo Zu, Hao Li, Jian Wang, Xinhong Yu, Wei Wang,